Unit+VI-Kinetics+&+Equilibrium

__Suggested Reading__
 * Chapter Twelve: Chemical Kinetics (p. 527-558)

__Learning Objectives__
 * Identify factors which affect reaction rates
 * Calculate the rate of production of a product or consumption of a reactant using mole ratios and the given rate
 * Determine the rate law for a reaction from given data, overall order, and value of the rate constant, inclusive of units
 * Determine the instantaneous rate of a reaction
 * Use integrated rate laws to determine concentration at a certain time, //t//, and create graphs to determine the order of a reaction
 * Determine the half-life a reaction
 * Write the rate law from a given mechanism given, the speeds of each elementary step
 * Write the overall reaction for a mechanism and identify catalysts and intermediates present
 * Determine the activation energy for the reaction using the Arrhenius equation
 * Graphically determine the activation energy using the Arrhenius equation

__Lecture Concepts__
 * Chemical Kinetics
 * Reaction Rates
 * Factors affecting reaction rates
 * Collision theory
 * Determination of Rate Law
 * Integrated Rate Law
 * Mechanisms
 * Catalysts/Activation energy

__Problem Set #6.1__
 * Chapter 12 → 11, 19, 21, 25, 29, 31, 39, 41, 51, 57, 59, 65

Activation Energy Lab Website: http://group.chem.iastate.edu/Greenbowe/sections/projectfolder/flashfiles/kinetics2/iodine_clock.html.

__Assignments__

__Suggested Reading__
 * Chapter 13: Chemical Equilibrium (p. 579-610)

__Learning Objectives__
 * Write the equilibrium expressions for a given reaction
 * Calculate Q and compare it to K to determine if a reaction is at equilibrium
 * Manipulate K if a reaction is reversed or multiplied by a coefficient
 * Calculate K from given equilibrium concentrations, or if given K and all except one equilibrium concentrations, solve for the missing value
 * Calculate equilibrium concentrations (for one of the missing variables) if given any two of the following values: K, the initial concentrations, and/or one equilibrium concentration
 * Do calculations involving gaseous equilibria, partial pressures, and Kp
 * Use Le Chatelier’s principle to determine in what direction the position of equilibrium will shift when a change is imposed

__Lecture Concepts__
 * Chemical Equilibrium
 * Definition of Equilibrium
 * Reaction quotient
 * Law of Mass Action & Equilibrium Constant
 * Application of Keq (Kc, Kp)
 * Gaseous Equilibria
 * Performing equilibrium calculations
 * Le Chatelier’s Principle

__Problem Set #6.2__
 * Chapter 13 → 16, 17, 19, 21, 33, 37, 39, 41, 53, 59, 61

Le Chatelier's Principle Online Activity Websites: http://www.instruction.greenriver.edu/kmarr/Chem%20163/Chem%20160%20PPT/Ch%2017%20Equilibrium/lechateliers_principal.swf http://www.harpercollege.edu/tm-ps/chm/100/dgodambe/thedisk/equil/8perform.htm

__Assignments__